BANERJEE, Ishita, Jaromír MAREK, Radovan HERCHEL a Mahammad ALI. Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies. Polyhedron. Velká Británie: Elsevier Science Ltd., 2010, roč. 29, č. 4, s. 1201-1208. ISSN 0277-5387. |
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@article{885666, author = {Banerjee, Ishita and Marek, Jaromír and Herchel, Radovan and Ali, Mahammad}, article_location = {Velká Británie}, article_number = {4}, keywords = {EE and EO bridging; Synthesis; Crystal structures; Ferro and antiferromagnetic coupling}, language = {eng}, issn = {0277-5387}, journal = {Polyhedron}, title = {Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies}, url = {http://dx.doi.org/10.1016/j.poly.2009.12.023}, volume = {29}, year = {2010} }
TY - JOUR ID - 885666 AU - Banerjee, Ishita - Marek, Jaromír - Herchel, Radovan - Ali, Mahammad PY - 2010 TI - Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies JF - Polyhedron VL - 29 IS - 4 SP - 1201-1208 EP - 1201-1208 PB - Elsevier Science Ltd. SN - 02775387 KW - EE and EO bridging KW - Synthesis KW - Crystal structures KW - Ferro and antiferromagnetic coupling UR - http://dx.doi.org/10.1016/j.poly.2009.12.023 N2 - Four azide bridged dinuclear copper(II) complexes have been synthesized, out of which complexes 1 and 2 have been characterized structurally. In Complex 1 the two bridging azide ligands have connected the two metal centers in an end-on (EO) fashion with aSP (asymmetric Square Pyramidal) geometry and showed an weak antiferromagnetic interaction. On the contrary, in complex 2, the two metal centers have been connected in end-to-end (EE) fashion exhibiting moderately strong ferromagnetic interaction. Cyclic voltammetric studies performed on all the four complexes show a reasonably good correlations. ER -
BANERJEE, Ishita, Jaromír MAREK, Radovan HERCHEL a Mahammad ALI. Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2010, roč.~29, č.~4, s.~1201-1208. ISSN~0277-5387.
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