| BUCHLOVIČ, Marian, Simona HEBANOVÁ a Milan POTÁČEK. 1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones. Tetrahedron. Oxford, England: Pergamon - Elsevier Science, 2012, roč. 68, č. 14, s. 3117-3122. ISSN 0040-4020. Dostupné z: https://dx.doi.org/10.1016/j.tet.2012.01.043. |
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@article{977506,
author = {Buchlovič, Marian and Hebanová, Simona and Potáček, Milan},
article_location = {Oxford, England},
article_number = {14},
doi = {http://dx.doi.org/10.1016/j.tet.2012.01.043},
keywords = {Cyclic nitrones; 1-3-Dipolar cycloadditions; Stereoselectives reactions; Dipolarophile; Nitrone complexes},
language = {eng},
issn = {0040-4020},
journal = {Tetrahedron},
title = {1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones},
volume = {68},
year = {2012}
}
TY - JOUR
ID - 977506
AU - Buchlovič, Marian - Hebanová, Simona - Potáček, Milan
PY - 2012
TI - 1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones
JF - Tetrahedron
VL - 68
IS - 14
SP - 3117-3122
EP - 3117-3122
PB - Pergamon - Elsevier Science
SN - 00404020
KW - Cyclic nitrones
KW - 1-3-Dipolar cycloadditions
KW - Stereoselectives reactions
KW - Dipolarophile
KW - Nitrone complexes
N2 - A new family of 5-membered cyclic nitrones bearing functional groups at positions 2,5 were tested in 1,3-cycloadditions with various dipolarophiles. Studied reactions offered corresponding cycloaducts as single diastereomers in high yields. The reaction scope was examined, 23 compounds were isolated and fully characterized. The comparison of the reactivity was done by a study of reaction conversions while different nitrones or dipolarophiles were used. In addition, we have studied the exceptional reactivity of nitrone bearing benzylamino group in position 2. The formation of nitrone complex and evaluation of its reactivity in 1,3-DC is presented.
ER -
BUCHLOVIČ, Marian, Simona HEBANOVÁ a Milan POTÁČEK. 1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones. \textit{Tetrahedron}. Oxford, England: Pergamon - Elsevier Science, 2012, roč.~68, č.~14, s.~3117-3122. ISSN~0040-4020. Dostupné z: https://dx.doi.org/10.1016/j.tet.2012.01.043.
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